Without even getting into judging or frowning upon a divorced woman, I don’t see most guys wanting to marry a girl who already has kids as a responsibility. When there is an option of a girl who doesn’t have that extra responsibility, I don’t see why he wouldn’t go with her, particularly in an arranged setting where he has no previous interaction with them. Sure, if he/family somehow know her and like her, then anything goes. But if that’s not the case, I don’t see a guy going for one with the extra baggage when there’s someone (as far as he knows) without it.
As for marrying to alleviate pain and all that, if you browse topics even on this forum, you can see the women’s side of the family will even look into the health of prospective grooms and even decline based on health problems. So it’s not just the men–anyone will try to avoid these situations that will complicate their lives even more. It goes both ways. And there’s nothing wrong with that. Also, though perhaps not to the same extent, a divorced man would also rank lower than his undivorced counterpart as a marriage prospect.