While you have every right to protect your siblings, stopping them from using the internet will not be a permanent or long term solution. Where there is a will, there is a way. They still will find a way to use the internet.
You need to sit down and talk to them properly regarding this, highlight your concerns and fears. They probably feel as though you have broken their trust, which is also something you should contemplate.
Over protecting someone, anyone, can have negative consequences too.
well said :-)